One teflon-like channelled nanoporous polymer with a chiral and new uninodal 4-connected net: sorption and catalytic properties |
| |
Authors: | Monge Angeles Snejko Natalia Gutiérrez-Puebla Enrique Medina Manuela Cascales Concepción Ruiz-Valero Caridad Iglesias Marta Gómez-Lor Berta |
| |
Affiliation: | Instituto de Ciencia de Materiales de Madrid (CSIC) Cantoblanco, 28049 Madrid, Spain. amonge@icmm.csic.es |
| |
Abstract: | Zn(C17H8F6O4) is the first example of a fluoro-lined nanotube organo-inorganic 3D polymeric chiral structure, which possesses two different types of isolated channels, one of them being laid out with a double spiral of CF3-groups from the ligand molecule; the structure is a new uninodal 4-connected net that only exists when bent ligands connect the centres, and the compound exhibits selective sorption and catalytic chiral recognition properties. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|