Preparation and spectroscopic and electrochemical properties of complexes of dibenzo-and dipyrido-substituted 1,4-diazines |
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| Authors: | O. A. Farus K. P. Balashev M. A. Ivanov T. A. Tkacheva A. G. Panova |
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| Affiliation: | (1) Herzen Russian State Pedagogical University, nab. r. Moiki 48, St. Petersburg, 191186, Russia |
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| Abstract: | The spectroscopic and electrochemical properties of palladium ethylenediamine complexes [Pd(N^N)En]Cl2 with 1,4-diazine derivatives of o-phenanthroline [(N^N) = dipyrido[a,c]phenazine (dppz), dipyrido[f,h]quinoxaline (dpq)] were studied in comparison with those of the free diimine (N^N) ligands, dibenzo-substituted 1,4-diazines [dibenzo[f,h]quinoxaline (dbq), dibenzo[a,c]phenazine (dbpz)], and cyclometallated dichloride [Pd(C^N)(μ-Cl)]2 and ethylenediamine [Pd(C^N)En]Cl complexes derived from dibenzo-substituted 1,4-diazines. |
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