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Synthesis and reaction of Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol with FeCl3 |
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| Authors: | Vukadin M Leovac Sla?ana B Novakovi? Goran A Bogdanovi? Milan D Joksovi? |
| Institution: | (1) Department of Chemistry, Faculty of Sciences, University of Novi Sad, Trg Dositeja Obradovića 3, Novi Sad, 21000, Serbia;(2) VINČA Institute of Nuclear Sciences, P.O. Box 522, Belgrade, 11001, Serbia;(3) Faculty of Science, Department of Chemistry, R. Domanovića 12, Kragujevac, 34000, Serbia |
| Abstract: | A potentially tridentate Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol was synthesized in the condensation reaction of 3-picolylamine and acetylacetone. The compound was characterized by 1H,13C-NMR and IR spectra. The reaction of Schiff base with Fe(III) in the acetone solution and the presence of pyridine led to its hydrolysis and the formation of the octahedral complex Fe(acac)Cl2(py)2]. The structure of the complex was determined by the single crystal X-ray diffraction analysis. The magnetic properties and the molar conductivity of the complex compound were also derived. |
| Keywords: | Schiff base 3-Picolylamine Acetylacetone Fe(III) complex Crystal structure |
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