Enantioselective total synthesis of valeriananoids A-C |
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| Authors: | Srikrishna A Satyanarayana G |
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| Institution: | Department of Organic Chemistry, Indian Institute of Science, Bangalore 560012, India. ask@orgchem.iisc.ernet.in |
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| Abstract: | reaction: see text] The first enantioselective total synthesis of valeriananoids A-C (-)-1-3 is reported starting from the readily available monoterpene (R)-carvone, employing a tandem intermolecular Michael addition-intramolecular Michael addition-alkylation sequence and an electron-transfer-mediated 6-endo-trig cyclization as key steps. |
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