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Recovery of PET-quenched fluorescent conjugated polymers with aza-15-crown-5 as pendant groups on interaction with ions
Authors:Jing Cao  Jun-xiang Feng  Shi Wu
Affiliation:1. College of Chemistry, Xiangtan University, Xiangtan, 411105, China
2. School of Pharmacy, Hubei University of Science and Technology, Xianning, 437100, China
Abstract:Novel conjugated polymers with aza-15-crown-5 as pendant groups, P1 were synthesized by the Sonogashira coupling reaction. The polymer P1 was found to show fluorescence enhancement response towards Ba2+. The gradual recovery and turning-point of emission intensity of polymers appeared in the addition of Ba2+, which provided good evidence for the fluorescence amplification mechanism of conjugated polymers.
Keywords:Conjugated polymer  Fluorescence recovery,
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