Character of hydrogen interaction with copper chromite |
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Authors: | I I Simentsova A V Khasin and T M Yurieva |
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Institution: | (1) Federal Scientific Center, Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia |
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Abstract: | Hydrogen bonding kinetics have been studied and water amounts produced in H2 interaction with copper chromite CuCr2O4 determined. Two possible interaction mechanisms are suggested: (1) a mechanism involving solid phase oxygen accompanied by water formation; (2) direct redox copper displacement from chromite by hydrogen that requires no oxygen. Initially, when the reaction occurs mainly on the surface, up to 40% of hydrogen is converted according to the first mechanism. Then, the process mainly occurs in the bulk via the second mechanism. Hydrogen sorption by copper chromite proved to be reversible. |
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Keywords: | Hydrogen copper chromite sorption kinetics catalyst activation hydrogenation |
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