Reaction of tris(2-hydroxyethyl)amine hydrochloride with zinc diacetate and bis(2-methylphenoxy)acetate |
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| Authors: | S. N. Adamovich R. G. Mirskov A. N. Mirskova M. G. Voronkov |
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| Affiliation: | 1.Favorskii Irkutsk Institute of Chemistry, Siberian Branch,Russian Academy of Sciences,Irkutsk,Russia |
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| Abstract: | Reaction of tris(2-hydroxyethyl)amine hydrochloride Cl− N+H(CH2CH2OH)3 with zinc diacetate and bis(2-methylphenoxy)acetate in the molar ratio 2: 1 results in complexes 2[Cl− N+H(CH2CH2OH)3]· Zn (OCOR)2 (I, II) R= Me (I), 2-MeC6H4OCH2 (II), which contain two protatrane cations linked with zinc diacylate by two coordination bonds HO → Zn. Complexes I and II are also formed by the reaction of the corresponding tris(2-hydroxyethyl)amine hydrochloride acylate RCOO−N+H(CH2CH2OH)3 with ZnCl2. The structure of complexes I, II is proved by elemental analysis, IR and 1H, 13C, 15N NMR spectroscopy. |
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