Secondary structure of globules of copolymers consisting of amphiphilic and hydrophilic units: Effect of potential range |
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Authors: | V A Ermilov V V Vasilevskaya A R Khokhlov |
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Institution: | (1) Laboratory of Polymer Chemistry, University of Helsinki, PB 55, Helsinki, 00014, HY, Finland;(2) Department of Chemistry, University of Montreal, CP 6128 succursale Centre-Ville, Montreal, H3C 3J7, Qc, Canada;(3) Faculty of Pharmacy, University of Montreal, CP 6128 succursale Centre-Ville, Montreal, H3C 3J7, QC, Canada |
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Abstract: | The relation of the coil-globule transition in macromolecules consisting of amphiphilic and hydrophilic monomer units to the
radius of action of the interaction potential is investigated by the method of computer-assisted experiments. The internal
structure of globules formed by such macromolecules is significantly dependent on the radius of action of the potential. In
the case of the long-range potential, the globule is characterized by the blob structure, while in the case of the short-range
potential, a quasi-helical structure forms. In this structure, the skeleton of a macromolecule forms a helical turn, and the
direction of twisting may vary from one turn to another. The coil-globule transition in such macromolecules proceeds through
formation of the necklace conformation from quasi-helical micelle beads. For sufficiently long macromolecules, the dimensions
of such globules are linearly dependent on the degree of polymerization. |
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