A new organic transformation by introducing crotyl/allyltrifluoroborates in cross-coupling reaction with aroyl chlorides |
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Authors: | Mohammad Al-Masum Kwei-Yu Liu |
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Institution: | Tennessee State University, Department of Chemistry, 3500 John A Merritt Blvd., Boswell 201, Nashville, TN 37209, USA |
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Abstract: | Microwave irradiated PdCl2(dtbpf) catalyzed direct cross-coupling reaction of aroyl chlorides with potassium crotyl/allyltrifluoroborates has been developed. Regioselectivity of the cross-coupling product is varied from crotyltrifluoroborate to allyltrifluoroborate. |
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Keywords: | Cross-coupling Potassium crotyl- and allyltrifluoroborates Aroyl chlorides Crotonophenones |
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