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Ultrahigh-frequency NMR of Tm3+ ions in single crystals of thulium ethylsulfate in high magnetic fields
Authors:D. I. Abubakirov  V. V. Naletov  M. S. Tagirov  D. A. Tayurskii  A. N. Yudin
Affiliation:(1) Department of Physics, Kazan State University, ul. Lenina 18, Kazan, 420008 Tatarstan, Russia;(2) Physics Department, Faculty of Science, Kanazawa University, 920-1192 Kanazawa, Japan
Abstract:Resonant transitions predicted earlier between low-lying electron-nuclear sublevels of the Tm3+ ground state were observed at frequencies up to 700 MHz in a dielectric Van Vleck paramagnet—thulium ethylsulfate single crystal. It is shown that, due to the distortion of the 4f-electron shell of a rare-earth ion in an applied magnetic field, the parameters of electron-nuclear interaction become field-dependent.
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