Copper(II) [(4-methylphenyl)sulfonyl]-1H-imino-(2-phenyl-2-oxazoline) complexes |
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| Authors: | Cabaleiro Santiago Pérez-Lourido Paulo Castro Jesús Romero Jaime García-Vázquez J Arturo Sousa Antonio |
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| Institution: | (1) Departamento de Química Inorgánica, Universidade de Vigo, 36200 Vigo, Galicia, Spain;(2) Departamento de Química Inorgánica, Universidade de Santiago de Compostela, 15706 Santiago de Compostela, Galicia, Spain |
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| Abstract: | Neutral copper complexes of the deprotonated (4-methylphenyl)sulfonyl]-1H-imino-(2-phenyl-2-oxazoline) proligands, HTs-ROz], R = H, 5-Me, 4-Me, 4-Et, 4-iPr, have been prepared by electrochemical oxidation of anodic copper in an MeCN solution of the corresponding proligand. The Cu(Ts-ROz)2] complexes were characterised by microanalysis, i.r. and electronic spectroscopies, and by e.p.r. and magnetic measurements. The crystal structures of HTs-5MeOz, Cu(Ts-Oz)2], Cu(Ts-5MeOz)2] and Cu(Ts-4MeOz)2] were determined by X-ray diffraction. |
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