Intensités des transitions optiques de [PtCl4]2− |
| |
Authors: | Claude Moncuit |
| |
Institution: | 1. Département de Physique, Université d'Orléans, France 2. Département de Recherches Physiques, Laboratoire associé au CNRS n0 71, Université Paris VI, France
|
| |
Abstract: | The oscillator strengths of the “d-d” transitions of the ion PtCl4]2? were calculated. The method, based on the evaluation of the MO of the distorted ion, gives results in good accordance with the experimental data. The transition to 1 B 1g (a 1g →b 1g * ), as a consequence of the participation of the orbital 6s, mixed with \(5d_{z^2 } \) in \(a_{1_g } ,a_{1_g } \) is characterized by a very low intensity in the case of thex,y polarization. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|