Synthesis,spectral and electrochemical characterization of (dithiocarbamato)(arylazoimidazole)Palladium(II) perchlorates |
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Authors: | Das Debasis Sinha Chittaranjan |
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Institution: | (1) Department of Chemistry, The University of Burdwan, Burdwan, 713 104, India |
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Abstract: | The ternary complexes Pd(RaaiX)(SS)ClO4) where RaaiX is a N(1)-alkyl-2-(arylazo)imidazole (p-RC6H4N =NC3H2NN(1) X; X = Me, or Et, and R = H, Me or Cl) and SS = N,N-diethyldithiocarbamate or morpholinedithiocarbamate have been prepared and characterized by elemental analysis, i.r., u.v.-vis.
and 1H-n.m.r. data. Electrochemical studies show azo reduction. The complexes are thermally unstable and decompose to bis(dithiocarbamato)palladium(II) in solution.
This revised version was published online in June 2006 with corrections to the Cover Date. |
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