Homogeneous liquid-liquid extraction by pH dependent phase separation with a fluorocarbon ionic surfactant and its application to the preconcentration of porphyrin compounds |
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Authors: | Shukuro Igarashi Takao Yotsuyanagi |
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Affiliation: | (1) Department of Molecular Chemistry and Engineering, Faculty of Engineering, Tohoku University, 980 Sendai, Japan |
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Abstract: | Aqueous perfluorooctanoate (PFOA–) solution of water-miscible organic solvent (SOLV), such as dioxane and acetone, was separated into two immiscible phases reversibly by charge neutralization of PFOA– ion with proton (H+) (pKa value of HPFOA was 1.01, atI = 0.1, 20 °C). The transparent heavier phase, in which HPFOA was concentrated quantitatively, consisted of three components in the molar ratio of HPFOASOLVH2O = 14.06.6 for acetone system, and 10.471.9 for dioxane system, respectively. This separation provides a new homogeneous liquid-liquid extraction method, which can be successfully applied to the ultra-high preconcentration of water-soluble porphyrin compounds: 104-fold concentration was achieved within 20 min. |
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Keywords: | homogeneous liquid-liquid extraction fluorocarbon surfactant pH-dependent phase separation porphyrin |
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