| Modification of Metal Complex on the StereoselectiveHydrogenation of 2,3-Butanedione |
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| 引用本文： | Yan LI,Han Fan LIU* PCLCC,Center for Molecular Science,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080. Modification of Metal Complex on the StereoselectiveHydrogenation of 2,3-Butanedione[J]. 中国化学快报, 2001, 0(2) |
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| 作者姓名： | Yan LI Han Fan LIU* PCLCC Center for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing 100080 |
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| 作者单位： | Yan LI，Han Fan LIU* PCLCC，Center for Molecular Science，Institute of Chemistry，Chinese Academy of Sciences，Beijing 100080 |
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| 摘 要： | Nanoscopic metal clusters, because of their substantial difference from metal atoms and bulk metals in size and structure, have attracted great interest especially in the field of catalysis1. It is well known that additives can markedly affect the properties of metal catalysts. The effect of metal ions has been well studied in the field of heterogeneous catalysis2. However, the study of metal complex effect is scarce. We have reported that the metal complex can considerably modulate both the a…
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Modification of Metal Complex on the Stereoselective Hydrogenation of 2,3-Butanedione |
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| Yan LI,Han Fan LIU PCLCC,Center for Molecular Science. Modification of Metal Complex on the Stereoselective Hydrogenation of 2,3-Butanedione[J]. Chinese Chemical Letters, 2001, 0(2) |
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| Authors: | Yan LI Han Fan LIU PCLCC Center for Molecular Science |
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| Affiliation: | Yan LI,Han Fan LIU* PCLCC,Center for Molecular Science,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080 |
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| Abstract: | The modification of some metal complexes on Pt/Al2O3 clusters leads to remarkable increases in both the activity and the selectivity for meso-2,3-butanediol in the stereoselective hydrogenation of 2,3-butanedione. |
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| Keywords: | Stereoselective hydrogenation 2 3-butanedione metal complex platinum cluster. |
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