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Hindered rotation in an "exploded" biphenyl
Authors:Miljanić Ognjen S  Han Sangdon  Holmes Daniel  Schaller Gaston R  Vollhardt K Peter C
Affiliation:Center for New Directions in Organic Synthesis, Department of Chemistry, University of California at Berkeley, and the Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720-1460, USA.
Abstract:The first cases of hindered rotation around the triple bond in simple diphenylacetylenes were observed, including that in chiral 2,2'-bis(trimethylsilyl)-6,6'-bis(dimethylthexylsilyl)diphenylacetylene.
Keywords:
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