New organic metals: Radical cation salts of bis(ethylenedioxo)tetrathiafulvalene with halide mercurate anions |
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| Authors: | E. I. Zhilyaeva S. A. Torunova R. N. Lyubovskaya R. B. Lyubovskii |
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| Affiliation: | (1) Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation |
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| Abstract: | Radical cation salts with halide mercurate anions were obtained by the electrochemical oxidation of bis(ethylenedioxo)tetrathiafulvalene (BEDO-TTF), and their conductivity was studied. The compounds (BEDO-TTF)4Hg3X8 (X = Cl or Br), (BEDO-TTF)4Hg3.5I9, and (BEDO-TTF)2HgBr3 possess the conductivity of the metallic type down to helium temperatures.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1167–1170, May, 1996. |
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| Keywords: | bis(ethylenedioxo)tetrathiafulvalene electrochemical oxidation radical cation salts halide mercurate anions organic metals conductivity |
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