Charge-transfer complexes of aroxymethyltriethylsilanes |
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| Authors: | N I Golovanova N I Shergina N F Chernov M G Voronkov |
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| Institution: | 1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR
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| Abstract: | | 1. |
The complexing of aroxymethyltriethylsilanes with tetracyanoethylene was studied spectrophotometrically. The same relation between the ionization potentials (ID) and the max of the charge-transfer bands for p-XC6H4OCH3 and p-XC6H4OCH2Si(C2H5)3, and also for various classes of aromatic compounds, shows that the investigated molecules are  donors.
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A decrease in the ID of the studied compounds Indicates that their -donor capacity is greater than that of the corresponding anisoles.
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