| 酞菁（H_2TAP）的X－射线光电子能谱（XPS） |
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| 引用本文： | 朱志昂,卜显和,刘月霞. 酞菁（H_2TAP）的X－射线光电子能谱（XPS）[J]. 化学研究与应用, 1996, 0(1) |
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| 作者姓名： | 朱志昂 卜显和 刘月霞 |
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| 作者单位： | 南开大学化学系 |
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| 摘 要： | 酞菁（Ｈ_２ＴＡＰ）的Ｘ－射线光电子能谱（ＸＰＳ）朱志昂，卜显和，刘月霞（南开大学化学系天津３０００７１）ＰａｕｌＧ．Ｇａｓｓｍａｎ（美国明尼苏达大学化学系）关键词酞青，ＸＰＳ，Ｃ１ｓ电子结合能，Ｎ１ｓ电子结合能酞菁及其金属配合物作为叶绿素，血红素的?..
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| 关 键 词： | 酞青，XPS，C1s电子结合能，N1s电子结合能 |
X-RAY PHYTOELECTRON SPECTROSCOPY OF TETRAAZAPORPHYRIN |
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| Zhu Zhiang, Bu Xianhuo, Liu Yuexia. X-RAY PHYTOELECTRON SPECTROSCOPY OF TETRAAZAPORPHYRIN[J]. Chemical Research and Application, 1996, 0(1) |
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| Authors: | Zhu Zhiang Bu Xianhuo Liu Yuexia |
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| Abstract: | Tetraazaporpyrin (H2TAP) was synthesized and purified. The X-ray photoelectron spectroscopy (XPS) of H_2TAP was measured using Perkin-Elmer PHI 5600 spectrometers. The H_2TAP showns two C1s peaks and three N1s peaks. C1s binding energies were 286. 28eV in eight carbon atoms bonding with hydrogen and 284. 76eV in other eight carbon atoms in H_2TAP. N1 s binding energies were 400. 27eV in two central nitrogens carrying hydrogen, N1s binding energies 398. 30eV assigned to other central nitrogens no carrying hydrogen, N1s binding energies of mesobridging aza nitrogens were 399.05eV. |
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| Keywords: | Tetraazaporphyrin (H_2TAP) X-ray photoelectron spectroscopy C1s binding energies N1s binding energies |
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