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Dioxygen Affinities and Catalytic Oxidation Performance of Cobalt (Ⅱ)Complexes with N—Aryl Hydroxamic Acid
引用本文:ChunChunZHANG WeiZENG JianZhangLI ShengYingQIN. Dioxygen Affinities and Catalytic Oxidation Performance of Cobalt (Ⅱ)Complexes with N—Aryl Hydroxamic Acid[J]. 中国化学快报, 2003, 14(6): 627-630
作者姓名:ChunChunZHANG WeiZENG JianZhangLI ShengYingQIN
作者单位:DepartmentofChemistry,SichuanUniversity,Chengdu610064
摘    要:The oxygenation of cobalt(Ⅱ) hydroxamates(CoL2) and its catalytic performance in oxidation of p-xylene to p-toluic acid (PTA) were examined.The effects of X and Y bonded to hydroxamate group on dioxygen affinities and catalytic oxidation performance were also investigated.

关 键 词:分子氧 亲合力 催化氧化反应 钴配合物 N-芳基异羟肟酸 催化剂

Dioxygen Affinities and Catalytic Oxidation Performance of Cobalt (Ⅱ) Complexes with N-Aryl Hydroxamic Acid
Chun Chun ZHANG,Wei ZENG,Jian Zhang LI,Sheng Ying QIN. Dioxygen Affinities and Catalytic Oxidation Performance of Cobalt (Ⅱ) Complexes with N-Aryl Hydroxamic Acid[J]. Chinese Chemical Letters, 2003, 14(6): 627-630
Authors:Chun Chun ZHANG  Wei ZENG  Jian Zhang LI  Sheng Ying QIN
Abstract:The oxygenation of cobalt (Ⅱ) hydroxamates (CoL2) and its catalytic performance inoxidation ofp-xylene to p-toluic acid (PTA) were examined. The effects of X and Y bonded tohydroxamate group on dioxygen affinities and catalytic oxidation performance were alsoinvestigated.
Keywords:dioxygen affinities  catalytic oxidation  p-xylene
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