| Heck Arylation of Cyclohexene Promoted by Ultrasonic and Micro wave in Ionic Liquid： a Novel Method of the Synthesis of 3-Naphthylcyclohexene |
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| 作者姓名： | Wen PEI Chen SHEN |
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| 作者单位： | Wen PEI?，Chen SHEN College of Chemical Engineering and Materials，Zhejiang University of Technology，Hangzhou 310014 |
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| 摘 要： | Palladium catalyzed arylation or vinylation of olefins by aryl halides are well known as the Mizoroki-Heck reaction and have proved to be of genuine synthetic utility for C-C bond formation1. Although a lot of progress has been made in Heck coupling react…
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| 关 键 词： | 3-萘基环己烯 Heck反应 Heck芳基化 有机合成 离子液体 超声波 微波 钯镊络合物 |
| 收稿时间： | 2006-08-31 |
Heck Arylation of Cyclohexene Promoted by Ultrasonic and Micro wave in Ionic Liquid: a Novel Method of the Synthesis of 3-Naphthylcyclohexene |
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| Wen PEI Chen SHEN.Heck Arylation of Cyclohexene Promoted by Ultrasonic and Micro wave in Ionic Liquid: a Novel Method of the Synthesis of 3-Naphthylcyclohexene[J].Chinese Chemical Letters,2006,17(12):1534-1536. |
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| Authors: | Wen PEI Chen SHEN |
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| Abstract: | Synthesis of 3-naphthylcyclohexene by the Heck reactions of bromonaphthalene and naphthyl triflates with cyclohexene catalyzed by palladiun and nickel complex (promoted by ultrasonic and microwave in ionic liquid of bmim]BF4]) were performed with high yield and good regioselectivity. This method has advantages of environmentally benign, generality, simplicity and potential for recycling of ionic liquid and catalyat. |
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| Keywords: | Naphthylcyclohexene palladium and nickel complex ionic liquid Heck reaction synthesis |
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