A novel, tandem construction of C-N and C-C bonds: facile and one-pot transformation of the Baylis-Hillman adducts into 2-benzazepines |
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Authors: | Basavaiah Deevi Satyanarayana Tummanapalli |
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Affiliation: | School of Chemistry, University of Hyderabad, Hyderabad 500 046, India. |
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Abstract: | A novel reaction involving tandem construction of C-N and C-C bonds via the simultaneous Ritter and Houben-Hoesch reactions on Baylis-Hillman adducts leading to a convenient, one-pot synthesis of 2-benzazepine derivatives is described. A facile stereoselective transformation of the Baylis-Hillman adducts into (E)- and (Z)-allyl amides is also presented. |
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