Selective 1,3-complexation of p-(t)Bu-calix[4]arene by [TiCp(2)Me(2) |
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Authors: | Petrella Antonella J Roberts Nicholas K Craig Donald C Raston Colin L Lamb Robert N |
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Institution: | School of Chemical Sciences, University of New South Wales, Sydney, Australia. |
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Abstract: | Reaction of p-(t)Bu-calix4]arene with dimethyl titanocene results in high yield selective 1,3-dimetallation of the calixarene in the cone conformation by selective cleavage of one methyl group. |
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