Regio- and enantioselective iridium-catalysed allylic aminations and alkylations of dienyl esters |
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Authors: | Lipowsky Gunter Helmchen Günter |
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Affiliation: | Organisch-Chemisches Institut der Ruprechts-Karls-Universit?t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany. |
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Abstract: | Regio- and enantioselective iridium-catalysed allylic aminations and alkylations of dienyl substrates are presented; using phosphorus amidite L1 as ligand, aminations provided ee values of up to 97% and alkylations of up to 90%. |
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