A three dimensional porous metal-organic framework [Fe4L6.(DMF)3.(H2O)10] constructed from neutral discrete Fe4L6 pyramids [H2L = 1,3-benzodihydroxamix acid |
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Authors: | Bai Yan Guo Dong Duan Chun-Ying Dang Dong-Bin Pang Ke-Liang Meng Qing-Jin |
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Affiliation: | Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China. |
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Abstract: | A 3-D porous zeolite-like metal-organic framework surviving guest removal is assembled from a well-defined tetrahedral Fe(4)L(6) cavity by the cooperativity of hydrogen bonds and [small pi]-[small pi] stacking. |
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