Structure and magnetism of a new pyrazolate bridged iron(II) spin crossover complex displaying a single HS-HS to LS-LS transition |
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| Authors: | Leita Ben A Moubaraki Boujemaa Murray Keith S Smith Jonathan P Cashion John D |
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| Affiliation: | School of Chemistry, Monash University, P.O Box 23, Clayton, Victoria, Australia. |
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| Abstract: | The dinuclear iron(II) complex [(pypzH)(NCSe)Fe([micro sign]-pypz)(2)Fe(NCSe)(pypzH)].2H(2)O displays a single, sharp spin crossover transition between the [HS-HS] and [LS-LS] states and is structurally characterised above and below the T(1/2)= 225 K value |
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