Unprecedented metal template effect on the coupling of dithiafulvene moieties |
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| Authors: | Lorcy Dominique Guerro Michel Pellon Pascal Carlier Roger |
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| Affiliation: | Synthèse et Electrosynthèse Organiques UMR-CNRS 6510-Université de Rennes 1, Campus de Beaulieu, Bat 10A, 35042 Rennes cedex, France. dominique.lorcy@univ-rennes1.fr |
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| Abstract: | Coordination of two dithiafulvenyldiphenylphosphines on a Mo(CO)(4) fragment allows a carbon-carbon bond formation upon oxidation, leading to a novel type of metallacycle substituted by a redox active vinylogous tetrathiafulvalene. |
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