The first ligand-modulated oxidative Heck vinylation. Efficient catalysis with molecular oxygen as palladium(0) oxidant |
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| Authors: | Andappan Murugaiah M S Nilsson Peter Larhed Mats |
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| Institution: | Box 574, Organic Pharmaceutical Chemistry, Department of Medicinal Chemistry, BMC, Uppsala, SE-75123, Sweden. |
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| Abstract: | The discovery of the first ligand-supported Pd(ii) catalysed oxidative Heck reaction with molecular oxygen as reoxidant and the scope with diverse arylboronic acids and olefins using only 1-2% of catalyst are reported. |
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