Spin dynamics in CuGeO3 studied by muon spin rotation

We report a muon spin rotation (SR) study of the magnetic properties of the Cu²⁺ quasi-one-dimensional CuGeO₃ system and its lightly-doped derivative Cu_0.97Zn_0.03GeO₃. Susceptibility measurements on CuGeO₃ show a sudden change in the vicinity of 14 K that has been interpreted before as a magnetic transition to a spin-Peierls state. SR shows no evidence of spin freezing below 14 K, implying that the transition is to a magnetic state with no static (random or ordered) electronic moments. A modest slowing down of the electronic spin dynamics is also identified at this temperature. Similarly, no evidence of a transition to a static magnetic state is found for Cu_0.97Zn_0.03GeO₃ whose susceptibility shows hysteretic behaviour between zero-field and field cooled measurements at 4 K, previously ascribed to spinglass-like behaviour. Given the nature of the muon spin as a local magnetic probe, the present results necessitate a re-interpretation of the origin of the susceptibility anomaly observed in the doped system.