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Synthesis and enantiomeric recognition studies of dialkyl-substituted 18-crown-6 ethers containing an acridine fluorophore unit |
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| Authors: | Júlia KertészIldikó Móczár Attila KormosPéter Baranyai Miklós KubinyiKlára Tóth Péter Huszthy |
| Institution: | a Research Group for Alkaloid Chemistry of the Hungarian Academy of Sciences, PO Box 91, H-1521 Budapest, Hungary b Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, PO Box 91, H-1521 Budapest, Hungary c Chemical Research Center, Hungarian Academy of Sciences, PO Box 17, H-1525 Budapest, Hungary d Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, PO Box 91, H-1521 Budapest, Hungary e Research Group of Technical Analytical Chemistry of the Hungarian Academy of Sciences, PO Box 91, H-1521 Budapest, Hungary |
| Abstract: | Selectivity of the reported dimethyl-substituted (R,R)-1, the diisobutyl-substituted (R,R)-2 acridino-18-crown-6 ethers and the newly synthesized acridino-crown ether (S,S)-3 containing the methyl groups one carbon-carbon bond further away from the acridine unit was studied towards the enantiomers of the hydrogen perchlorate salts of α-phenylethylamine, α-(1-naphthyl)ethylamine, phenylglycine methyl ester and phenylalanine methyl ester using fluorescence. |
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