Development of a generalized phenomenological model describing the kinetics of the enzymatic hydrolysis of NaOH-treated pine wood |
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Authors: | J C Parajó J L Alonso V Santos |
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Institution: | (1) Department of Chemical Engineering, University of Vigo Campus Orense), Faculty of Sciences, Las Lagunas, 32004 Orense, Spain |
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Abstract: | Pinus pinaster wood samples were treated during 3 h with alkaline solutions (containing 1, 5.5, or 10 weight percent NaOH) at 100, 115,
or 130‡C using liquor/wood ratios of 6, 8, or 10 g/g. The solid residues obtained in treatments were used as substrates for
enzymatic hydrolysis. In the hydrolysis assays, the reaction time (in the range 0–48 h) was considered as an operational variable.
The cellulose conversion achieved at the end of assays were highest for samples pretreated at high temperature and high alkali
concentration using low liquor/wood ratios. The experimental results obtained in each hydrolysis trial were fitted to an empirical
model based on the assumption that the cellulose contained in substrates was composed by two fractions having different susceptibility
to hydrolysis. The kinetic parameters obtained for the various experiments performed were correlated with the operational
variables by means of empirical, statistically significant equations, which provided a generalized interpretation of the process. |
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Keywords: | Alkaline treatments cellulose enzymatic hydrolysis kinetic modeling pine wood |
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