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Green synthesis of methyl trifluoropyruvate catalyzed by solid acids |
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| Authors: | Sergey A Lermontov Lyudmila L Ushakova Nina V Kuryleva |
| Institution: | aInstitute of Physiologically Active Compounds, Russian Academy of Sciences, Chernogolovka, Moscow Region 142432, Severny proezd 1, Russia |
| Abstract: | Solid acids – NiSO4/Al2O3, Fe2(SO4)3/Al2O3 and TiO2/SO42− – appeared to be effective catalysts for the acid catalyzed synthesis of methyl ester of trifluoropyruvic acid. They are active at 150–180 °C. |
| Keywords: | Methyl ester of trifluoropyruvic acid Solid acids Superacids Hexafluoropropylene oxide |
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