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Preparation and characterization of nitrogen-doped titanium dioxides
摘    要:A type of high visible-light active titanium oxinitride(TiO2-xNx) powder was prepared by a simple proc-ess:the calcination of the hydrated titanium dioxide at the atmosphere of ammonia-argon using a tu-bular electric furnace at high temperatures. The hydrated titanium dioxide was synthesized as the precursor of TiO2-xNx using titanic acid as raw material,which came from sulfate technique of produc-ing titanium white. The effects of temperature and reaction time on the nitrogen content,grain size and crystal structure were studied. The visible-light activity and photocatalysis capability of the powder were also investigated.

收稿时间:2005-10-25
修稿时间:2006-03-24

Preparation and characterization of nitrogen-doped titanium dioxides
Zhu GuoPing,Zhou KangGen. Preparation and characterization of nitrogen-doped titanium dioxides[J]. Science in China(Chemistry), 2007, 50(2): 212-216. DOI: 10.1007/s11426-007-0008-x
Authors:Zhu GuoPing  Zhou KangGen
Affiliation:1. Environmental Science Research & Design Institute of Zhejiang Province, Hangzhou 310007, China
2. Department of Environmental Engineering, School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China
Abstract:A type of high visible-light active titanium oxinitride(TiO2-xNx) powder was prepared by a simple proc-ess:the calcination of the hydrated titanium dioxide at the atmosphere of ammonia-argon using a tu-bular electric furnace at high temperatures. The hydrated titanium dioxide was synthesized as the precursor of TiO2-xNx using titanic acid as raw material,which came from sulfate technique of produc-ing titanium white. The effects of temperature and reaction time on the nitrogen content,grain size and crystal structure were studied. The visible-light activity and photocatalysis capability of the powder were also investigated.
Keywords:nitrogen-doped titanium dioxides  visible-light activity  photocatalysis  titanium oxinitride
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