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The effects of wood-flour on combustion and thermal degradation behaviors of PVC in wood-flour/poly(vinyl chloride) composites
Authors:Xiao-yan Bai   Qing-wen Wang   Shu-juan Sui  Chun-sheng Zhang
Affiliation:a Life Science and Chemistry Department, Hulunbeir College, Inner Mongolia 021008, PR China;b Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin 150040, PR China;c Faculty of Administrative Sciences Hulunbeir, Inner Mongolia, Hailar 021008, PR China
Abstract:The effects of wood-flour on combustion and thermal degradation behaviors of PVC in wood-flour/poly (vinyl chloride) composites (WF-PVC) were investigated by using cone calorimeter (CONE) and TGA. The results show that thermal degradation behavior of WF-PVC composites has obvious characteristics of that of PVC. Interactions occur between wood-flour and PVC during the combustion and thermal degradation of WF-PVC composites. The thermal degradation of wood-flour can be accelerated by pure PVC. Moreover, the char formation can be raised by adding wood-flour to PVC. Compared with PVC at all flaming stage, when heat flux is kept at 50 kW m−2, the average heat release rate (av-HRR), the total heat release (THR), the total smoke production (TSP) and the average specific extinction area (av-SEA) of WF-PVC composites are respectively reduced by 44%, 9.2%, 25.8% and 29.9%. In WF-PVC composites, the wood-flour has remarkable effects on the properties of heat release and smoke release of PVC.
Keywords:Cone calorimeter   Combustion   Thermo gravimetric analysis (TGA)   Thermal degradation   Wood-flour/poly (vinyl chloride) composites
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