| 三桥连双铁(Ⅲ)配合物[Fe2(IDB)2(O)(CH3CO2)2]Cl2·CH3OH的晶体结构及其傅立叶变换拉曼光谱 |
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| 引用本文： | 叶勇,廖展如,向道凤,胡继明,曾云鹗.三桥连双铁(Ⅲ)配合物[Fe2(IDB)2(O)(CH3CO2)2]Cl2·CH3OH的晶体结构及其傅立叶变换拉曼光谱[J].光散射学报,2001,13(3):179-182. |
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| 作者姓名： | 叶勇 廖展如 向道凤 胡继明 曾云鹗 |
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| 摘 要： | 合成了一种新的三桥连双铁(Ⅲ)配合物Fe2(IDB)2(O)(CH3CO2)2]Cl2·CH3OH,IDB为N,N'-di(2'-benzimidazolyl
methyl) imine,利用单晶x射线衍射及其它谱学方法对所合成配合物进行了表征.每个双核单元的两个铁原子均通过一个氧原子和两个醋酸根连接,每个铁原子同时还与位于桥氧原子对位的三齿配体IDB重脂肪链上氮原子相结合,每个铁(Ⅲ)中心为一变形八面体结构.对该新化合物的拉曼光谱进行了研究并对一些谱峰进行了归属.
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Crystal Structure and
FT-Raman Spectroscopy of a Novel Triply Bridged Diiron ( |
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| Abstract.Crystal Structure and
FT-Raman Spectroscopy of a Novel Triply Bridged Diiron ([J].Chinese Journal of Light Scattering,2001,13(3):179-182. |
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| Authors: | Abstract |
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| Abstract: | A triply bridged dirron ( Ⅲ ) complex Fe2(IDB)2(O) (CH3CO2)2]Cl2CH3OH, in which IDB is N, N' -di(2' -benzimidazolyl methyl) imine, has been synthesized and characterized by single - crystal X - ray diffractometry and spectrometry. Both iron( Ⅲ ) atoms of the binuclear unit are bridged by one oxy atom and two acetate groups. Each iron atom is also bound to facially - coordinating tridentate IDB ligand with the aliphatic nitrogen donor situated trans to theμ- oxy atom. Each iron ( m ) centers is in a distorted octahedral symmetry. The Raman spectroscopy of the novel complexes have been studied and some peak have been attributed. |
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| Keywords: | Bridged dirron (Ⅲ) complex crystal synthesis FT-Raman Spectra |
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