Novel nanocomposite membranes prepared with PVC/ABS and silica nanoparticles for C2H6/CH4 separation |
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Authors: | Mahmoud Salimi Vahid Pirouzfar Ehsan Kianfar |
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Affiliation: | 1.Department of Chemical Engineering, Arak Branch,Islamic Azad University,Arak,Iran;2.Young Researchers and Elite Club, Central Tehran Branch,Islamic Azad University,Tehran,Iran |
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Abstract: | Composite membranes based on polyvinyl chloride and acrylonitrile butadiene styrene (ABS) copolymer have been prepared and then filled with 2–8 wt % of silica nanoparticles. Membranes were fabricated by solution casting method using dimethylacetamide. The performance of prepared membranes were studied for methane and ethane at the feed pressure of 1.0, 1.5, 2.0, and 3.0 bar at 35°C. By increasing the percentage of ABS, permeability of methane and ethane increased. In addition, by adding the silica nanoparticles in the membrane, permeability of gas increased in all cases. The highest gas pair selectivity for C2H6/CH4 could be obtained from PVC/BS (20 wt %) which loaded with 8 wt % of silica nanoparticles. The results of this study suggest that high performance gas separation nanocomposite membranes can be attained by adopting a judicious combination of blending technique for polymeric membrane, optimized loading percentage, and feed operating conditions. |
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