| SYNTHESIS AND CHARACTERIZATION OF A NEW COMBLIKE POLYMER BASED ON POLY (VINYL METHYL ETHER-ALT-MALEIC ANHYDRIDE) BACKBONE |
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| 作者姓名： | 丁黎明 林云青 周子南 倪建龙 陈东霖 |
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| 作者单位： | Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022 |
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| 摘 要： | A new comblike polymer host for polymer electrolyte was synthesized by reactingmonomethyl ether of poly (ethylene glycol) with poly (vinyl methyl ether alt-maleic anhydride)and endcapping the residual carboxylic acid with methanol. Butanone was selected as a solventfor the esterification in order to obtain a completely soluble product. The synthesis processwas traced through by IR. Compared with the model compounds, the presumed structure ofthis comblike polymer has been proved to be valid by ~(13)C NMR. The comb polymer is a whiterubbery solid. It can be dissolved in butanone and THF, and manifests good film formingability.
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| 收稿时间： | 1994-04-15 |
SYNTHESIS AND CHARACTERIZATION OF A NEW COMBLIKE POLYMER BASED ON POLY (VINYL METHYL ETHER-ALT-MALEIC ANHYDRIDE) BACKBONE |
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| DING Liming,LIN Yunqing,ZHOU Zinan,NI Jianlong,CHEN Donglin.SYNTHESIS AND CHARACTERIZATION OF A NEW COMBLIKE POLYMER BASED ON POLY (VINYL METHYL ETHER-ALT-MALEIC ANHYDRIDE) BACKBONE[J].Chinese Journal of Polymer Science,1995,0(3):264-272. |
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| Authors: | DING Liming LIN Yunqing ZHOU Zinan NI Jianlong CHEN Donglin |
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| Institution: | Changchun Institute of Applied Chemistry; Academia Sinica; Changchun 130022 |
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| Abstract: | A new comblike polymer host for polymer electrolyte was synthesized by reactingmonomethyl ether of poly (ethylene glycol) with poly (vinyl methyl ether alt-maleic anhydride)and endcapping the residual carboxylic acid with methanol. Butanone was selected as a solventfor the esterification in order to obtain a completely soluble product. The synthesis processwas traced through by IR. Compared with the model compounds, the presumed structure ofthis comblike polymer has been proved to be valid by ~(13)C NMR. The comb polymer is a whiterubbery solid. It can be dissolved in butanone and THF, and manifests good film formingability. |
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| Keywords: | Comblike polymer Poly (vinyl methyl ether-alt-maleic anhydride) Esterification Polymer electrolytes IR spectra ~(13)C NMR spectra |
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