Co(II)-Co(II) paddlewheel complex with a redox-active ligand derived from TTF |
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Authors: | Benbellat Noura Gavrilenko Konstantin S Le Gal Yann Cador Olivier Golhen Stéphane Gouasmia Abdelkrim Fabre Jean-Marc Ouahab Lahcène |
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Affiliation: | Organométalliques et Matériaux Moléculaires, UMR 6226 CNRS, Université de Rennes 1, Sciences Chimiques de Rennes, 35042 Rennes Cedex, France. |
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Abstract: | A new trimethyltetrathiafulvalene (Me3TTF) derivative Me3TTF-CH=CH-py bearing a pyridyl was synthesized and coordinated to a cobalt(II) benzoate dimer, having paddlewheel core structure, leading to a complex formulated as Co2(PhCOO)4(Me3TTF-CH=CH-py)2. Single-crystal X-ray diffraction studies of the complex performed at 293 and 100 K evidenced the existence of a weak metal-metal interaction. Magnetic studies revealed an antiferromagnetic behavior, which is explained as the result of the direct exchange between metal centers. |
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