| 6-氧基嘌呤与3d金属高氧酸盐的配合物 |
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| 作者姓名： | Chester M. Mikulski Matthew K. Kurlan Monica Bayne Michele Gaul Nicholas M. Karayannis |
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| 作者单位： | Department of Chemistry &Physics，Beaver College，Department of Chemistry &Physics，Beaver College，Department of Chemistry &Physics，Beaver College，Department of Chemistry &Physics，Beaver College，Amoco Chemical Company Glenside，PA 19038，U.S.A.，Glenside，PA 19038，U.S.A.，Glenside，PA 19038，U.S.A.，Glenside，PA 19038，U.S.A.，P.O.Box 400，Naperville，IL 60566，U.S.A. |
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| 摘 要： | 题配合物的合成是将金属高氯酸盐1.25毫摩溶于35毫升乙酸乙酯和15毫升乙醇-原甲酸三乙酯混合溶剂内,然后加6-氧基嘌吟(hxH)2.5毫摩(对于M~(2+))或3.75毫摩(对于M~(3+));将整个混合物回流6小时,冷至室温后,加无水乙醚15—20毫升,加微热以使体积减至约20毫升,将固体过滤分出,用乙醚30毫升洗涤,贮于真空无水CaSO_4干燥器内,所得产物含较高的氧基嘌吟与金属比(4:1或3:1),根据分析结果,分下列类型:M(hx)(hxH)(Cl0_4)ClO_4(M=Cr,Fe),M(hx)(hxH)_3(H_2O)]ClO_4(M=Mn,Cu,Zn),M(hx)(hxH_2)(H_2O)(ClO_4)](M=Fe,Ni)和Co(hx)(hxH)]ClO_4。这些新配合物皆不溶于有机溶剂。光谱表征表明高氯酸根在M=Mn~(2+),Co~(2+),Cu~(2+),Zn~(2+)配合物内皆为外界离子,而在M=Fe~(2+),Ni~(2+)配合物内则为单齿配体,在M~(3+)(Cr,Fe)配合物内,一为离子,另一为单配体。除Co为5配位外,余皆为6配位。所有这些新配合物皆以hx为桥连配体,通过N_3,N_7,形成链状聚合物。
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| 关 键 词： | 次黄嘌呤 金属高氯酸盐 配合物 |
| 收稿时间： | 1987/8/14 0:00:00 |
HYPOXANTHINE COMPLEXES WITH 3d METAL PERCHLORATES |
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| Chester M. Mikulski,Matthew K. Kurlan,Monica Bayne,Michele Gaul,Nicholas M. Karayannis.HYPOXANTHINE COMPLEXES WITH 3d METAL PERCHLORATES[J].Chinese Journal of Inorganic Chemistry,1988,4(3):83-88. |
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| Authors: | Chester M Mikulski Matthew K Kurlan Monica Bayne Michele Gaul and Nicholas M Karayannis |
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| Institution: | Department of Chemistry &Physics, Beaver College, Glenside, PA 19038, U.S.A.,Department of Chemistry &Physics, Beaver College, Glenside, PA 19038, U.S.A.,Department of Chemistry &Physics, Beaver College, Glenside, PA 19038, U.S.A.,Department of Chemistry &Physics, Beaver College, Glenside, PA 19038, U.S.A. and Amoco Chemical Company, P.O.Box 400, Naperville, IL 60566, U.S.A. |
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| Abstract: | |
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| Keywords: | hypoxanthine metal perchlorate complex |
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