Complexes of 2,5-dihydroxy-1,4-benzoquinone and chloranilic acid with second and third row transition elements |
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| Authors: | Mostafa Sahar I |
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| Institution: | (1) Department of Chemistry, Faculty of Science, Mansoura University, Mansoura, Egypt |
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| Abstract: | The synthesis of new 2,5-dihydroxy-1,4-benzoquinone (H2DHBQ) and chloranilic acid (H2CA) complexes cis-Mo2O5L2]2– (L = DHBQ, CA), W2O5(DHBQ)2]2–, WO2(CA)2]2–, trans-UO2(DHBQ)]·H2O, and trans-UO2(CA)2]2– is described. Raman, i.r., 1H and 13C n.m.r spectra of the ligands and their complexes are reported and their structures discussed. |
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