A new family of supramolecular multiferrocenyl rhomboids:Synthesis,characterization,and their electrochemical behavior |
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| Authors: | Jiang-Kun Ou-Yang Li-Jun Chen Lin Xu Cui-Hong Wang Hai-Bo Yang Shanghai |
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| Affiliation: | Jiang-Kun Ou-Yang,Li-Jun Chen,Lin Xu,Cui-Hong Wang,Hai-Bo Yang* Shanghai Key Laboratory of Green Chemistry and Chemical Processes,Department of Chemistry,East China Normal University,Shanghai 200062,China |
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| Abstract: | Two novel, supramolecular, multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60° ferrocenyl donor precursor 1 via coordination-driven self-assembly. The structures of all multiferrocenyl rhomboids were characterized by multinuclear NMR (1H and 31P), CSI–TOF-MS, and PM6 semi-empirical molecular simulation, and their electrochemical behaviors have been investigated. |
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| Keywords: | Supromolecular metallacycle Coordination-driven self-assembly Multiferrocenyl rhomboid Electrochemical behavior |
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