Ruthenium carborane complexes in the controlled radical polymerization of methyl methacrylate |
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| Authors: | E. V. Kolyakina I. D. Grishin D. N. Cheredilin F. M. Dolgushin I. T. Chizhevsky D. F. Grishin |
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| Affiliation: | (1) Research Institute of Chemistry of the N. I. Lobachevsky Nizhnii Novgorod State University, 23, building 5, prosp. Gagarina, 603950 Nizhnii Novgorod, Russian Federation;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation |
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| Abstract: | New initiators based on closo-and exo-nido-ruthenacarboranes with phosphine and diphosphine ligands were proposed as chain growth regulators. They allow conducting the controlled synthesis of poly(methyl methacrylate) under radical initiation conditions. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 85–89, January, 2006. |
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| Keywords: | ruthenium carborane complexes methyl methacrylate controlled radical polymerization |
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