| 氨基磺酸催化合成丁二酸二丁酯 |
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| 引用本文： | 刘文奇,俞善信,张鲁西.氨基磺酸催化合成丁二酸二丁酯[J].合成化学,2004,12(4):381-382,393,J004. |
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| 作者姓名： | 刘文奇 俞善信 张鲁西 |
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| 作者单位： | 湘南学院化学系,湖南,郴州,423000;湖南师范大学化学化工学院,湖南,长沙,410081 |
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| 基金项目： | 国家化学教育基地建设项目资助 ( 0 2 12CC3 16) |
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| 摘 要： | 研究了氨基磺酸代替硫酸作为酯催化剂，由丁二酸与正丁醇合成丁二酸二丁酯的反应，考察了反应的影响因素及氨基磺酸的重复使用性能。丁二酸3．0g(250mmol)，n(丁二酸)：n(正丁醇)：n(氨基磺酸)=1．00：8．00：0．31，回流分水60min，酯收率97．4％。另外，还催化合成了癸二酸二丁酯、己二酸二丁酯和马来酸二丁酯。
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| 关 键 词： | 丁二酸二丁酯 合成 氨基磺酸 催化 |
| 文章编号： | 1005-1511(2004)04-0381-02 |
Synthesis of Dibutyl Succinate Catalyzed by Amino Sulfonic Acid |
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| LIU Wen-qi ,YU Shan-xin ,ZHANG Lu-xi.Synthesis of Dibutyl Succinate Catalyzed by Amino Sulfonic Acid[J].Chinese Journal of Synthetic Chemistry,2004,12(4):381-382,393,J004. |
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| Authors: | LIU Wen-qi YU Shan-xin ZHANG Lu-xi |
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| Institution: | LIU Wen-qi 1,YU Shan-xin 2,ZHANG Lu-xi 2 |
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| Abstract: | Dibutyl succinate was synthesized from succinic acid and n-butyl alcohol using amino sulfonic acid as a catalyst. The influent factors on the reaction and the reuseability of the calalyst were investigated. The yield of the ester could reach 97.4% under the optimum reaction conditions. Dibutyl sebacate, dibutyl adipate and dibutyl maleate were also synthesized using amino sulfonic acid as a calalyst. |
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| Keywords: | dibutyl succinate synthesis amino sulfonic acid catalysis |
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