| 聚合物假冠醚研究(VI) 以苯环为端基的[2,2,2]开链穴醚及其酚醛型聚合物的合成与吸附性能 |
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| 引用本文： | 刘淑芬,孙琳,刘军深,唐清华,张江,房新强,宋立美,韩丽.聚合物假冠醚研究(VI) 以苯环为端基的[2,2,2]开链穴醚及其酚醛型聚合物的合成与吸附性能[J].离子交换与吸附,2005(6). |
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| 作者姓名： | 刘淑芬 孙琳 刘军深 唐清华 张江 房新强 宋立美 韩丽 |
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| 作者单位： | 烟台师范学院化学与材料科学学院 烟台264025 |
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| 基金项目： | 烟台师院绿色有机化学重点研究项目 |
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| 摘 要： | 以2-苯氧乙醇为起始原料,合成了以苯环为端基的2,2,2]开链穴醚(三足体)及其酚醛型聚合物,测定了其对金属离子的吸附性能。结果表明,开链穴醚及其聚合物对Fe3+具有良好的选择吸附性能,吸附容量达1.74mmol/g(20℃)。同时测试了反应物的摩尔比、反应温度、Fe3+离子浓度和吸附时间对聚合物吸附Fe3+的影响。
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| 关 键 词： | 开链穴醚 聚合物 合成 吸附 |
STUDIES ON POLYMER PSEUDO CROWN ETHER(VI) Synthesis and Adsorption Properties of [2,2,2]-Open Chain Cryptand Containing end group Phenyl and Its Phenolic Polymers |
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| LIU Shufen SU N Lin LIU Junshen TANG Qinghua ZHANG Jiang FANG Xinqiang SONG Limei HAN Li School of Chemistry and Material Science,Yantai Normal University,Yantai ,China.STUDIES ON POLYMER PSEUDO CROWN ETHER(VI) Synthesis and Adsorption Properties of [2,2,2]-Open Chain Cryptand Containing end group Phenyl and Its Phenolic Polymers[J].Ion Exchange and Adsorption,2005(6). |
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| Authors: | LIU Shufen SU N Lin LIU Junshen TANG Qinghua ZHANG Jiang FANG Xinqiang SONG Limei HAN Li School of Chemistry and Material Science Yantai Normal University Yantai China |
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| Institution: | LIU Shufen SU N Lin LIU Junshen TANG Qinghua ZHANG Jiang FANG Xinqiang SONG Limei HAN Li School of Chemistry and Material Science,Yantai Normal University,Yantai 264025,China |
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| Abstract: | Using 2-phenoxyethanol as initial material,a 2,2,2]-open chain cryptand(tripodand)containing end group phenyl and its phenolic polymers were synthesized.The static adsorption properties of synthetic products for normal metallic ions were tested.The results showed that they have good adsorption selectivity properties for Fe3+ and the capacities of adsorption were 1.74mmol/g.The influences of reactantic molecular proportion and,reactive temperature,ionic concentration and adsorptive time on adsorption properties were in investigated. |
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| Keywords: | Open chain cryptand Polymer Synthesis Adsorption |
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