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阴离子对阳离子表面活性剂在Al(OH)3、CaCO3粉体上吸附的影响
引用本文:张智宏,沈钟,邵长生.阴离子对阳离子表面活性剂在Al(OH)3、CaCO3粉体上吸附的影响[J].无机化学学报,1999,15(4):451-456.
作者姓名:张智宏  沈钟  邵长生
作者单位:江苏石油化工学院化学工程系,常州,213016
基金项目:中国石油化工总公司资助
摘    要:研究了阳离子表面活性剂十六烷基二甲基烯丙基氯化铵(CDAAC)在Al(OH)3/水、CaCO3/水界面上的吸附,探讨了无机阴离子对吸附量及表面电荷的影响,测定了样品的接触角和比表面。结果表明PO3-4的加入可提高Al(OH)3、CaCO3表面负电荷,有利于吸附,经吸附改性后的样品具有憎水性。

关 键 词:改性  Zeta电位  氢氧化铝  碳酸钙

THE EFFECTS OF ANION ON ADSORPTION OF CATIONICS ON Al(OH)3 AND CaCO3 PARTICLES
ZHANG Zhi-Hong,SEN Zhong and SHAO Chang-Sheng.THE EFFECTS OF ANION ON ADSORPTION OF CATIONICS ON Al(OH)3 AND CaCO3 PARTICLES[J].Chinese Journal of Inorganic Chemistry,1999,15(4):451-456.
Authors:ZHANG Zhi-Hong  SEN Zhong and SHAO Chang-Sheng
Institution:Jiangsu Institute of Petrochemical technology, Changzhou 213016,Jiangsu Institute of Petrochemical technology, Changzhou 213016 and Jiangsu Institute of Petrochemical technology, Changzhou 213016
Abstract:In this paper, adsorption of cationics cetyl dimethyl allyl ammonium chloride (CDAAC) on Al(OH)3 and CaCO3 particles were studied. The effects of adding inorganic anion on adsorption amount and interface charge were investigated. The specific surface areas and contact angles of samples were determined. The results showed that adding PO3-4 was favourable to adsorption account for increasing interface negative charge, modification samples were hydrophobic.
Keywords:modification  Zeta potential  aluminium hydroxide  calcium carbonate
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