The cis-Re(Ph2PCH2CH2PPh2)2)+ metal centre. Synthesis and molecular structure of the dinitrile complex cis-[Re(NCC6H4Me-4 2(Ph 2 PCH 2 CH 2 PPh 2 2 ][BF4] |
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| Institution: | 1. LPGP, Univ. Paris-Sud/CNRS, Université Paris-Saclay, 91405 Orsay, France;2. NIMBE, CEA/CNRS, Université Paris-Saclay, 91191 Gif-sur-Yvette, France;3. SPEC, CEA/CNRS, Université Paris-Saclay, 91191 Gif-sur-Yvette, France;4. GeePs, CNRS UMR8507, CentraleSupelec, Univ Paris-Sud, Sorbonne Universités-UPMC Univ Paris 06, 91192 Gif-sur-Yvette Cedex, France;5. LAPA-IRAMAT, NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay, 91191 Gif-sur-Yvette cedex, France;1. University at Buffalo, State University of New York, Buffalo, NY, United States of America;2. Roswell Park Comprehensive Cancer Center, Buffalo, NY, United States of America;3. University of Texas Southwestern Medical Center, Dallas, TX, United States of America;4. Cleveland Clinic Taussig Cancer Institute, Cleveland, OH, United States of America |
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| Abstract: | Reaction of NCC6H4X-4 (X Me, OMe, or Cl) with trans-ReCl(N2)(dppe)2] (dppe Ph2PCH2CH2PPh2), at room temperature, in the presence of TlBF4], gives the corresponding complexes cis-Re(NCC6H4X-4)2(dppe)2]BF4] (1); the crystal structure of 1 (X Me) has been determined by single crystal X-ray diffraction analysis. |
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