Association and segregation in aqueous polymer/polymer,polymer/surfactant,and surfactant/surfactant mixtures: similarities and differences |
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| Institution: | 1. Department of Chemical and Pharmaceutical Engineering, Faculty of Chemistry and Pharmacy, Sofia University, Sofia 1164, Bulgaria;2. Unilever Research & Development Vlaardingen, 3133AT Vlaardingen, the Netherlands;3. Laboratory of Physical Chemistry and Colloid Science, Wageningen University, 6703 HB Wageningen, the Netherlands;4. Department of Mechanical Engineering, University College London, WC1E 7JE, UK;5. Unilever Research & Development Port Sunlight, Bebington CH63 3JW, UK;1. School of Light Industry, Beijing Technology and Business University, Beijing 100048, PR China;2. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, TIPC, CAS, Beijing 100190, PR China |
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| Abstract: | Recent experimental findings on the phase behaviour of aqueous polymer/surfactant mixtures are reviewed and compared with the phase behaviour of “analogous” polymer/polymer or surfactant/surfactant mixtures, which is also reviewed. Polyelectrolyte effects are given special consideration. Attention is drawn to the polymer aspect of a surfactant aggregate, and, also, to the surfactant aspect of an hydrophobe-modified polymer. It is proposed that a consideration of these aspects should be helpful in predicting the phase behaviour of polymer/surfactant mixtures. |
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