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Interaction-induced contribution to changes in the infrared spectrum of hydrogen-bonded complexes
Affiliation:1. College of Physics, Sichuan University, Chengdu 610065, China;2. Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China
Abstract:An attempt to include interaction-induced effects into the study of absorption in H-bonded complexes is presented. The IR band shapes of the νs(OH) mode in phenol, 2,4,6-trimethylphenol, 2,6-dichloro-4-nitrophenol, and dimethylamine with nitriles or pyridine derivatives have been studied in terms of the dipolar coupling theory.
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