Charge separation reactions of the CF2+ and CCl2+ dications |
| |
| Affiliation: | 1. Atomic, Molecular, and Optical Physics Laboratory, RIKEN, Saitama 351-0198, Japan;2. Department of Physics, Tokyo Metropolitan University, 192-0397 Tokyo, Japan;1. Institute of Spectroscopy, Russian Academy of Sciences, Fizicheskaya Str. 5, 108840 Troitsk, Moscow, Russia;2. I. Physikalisches Institut, University of Cologne, Zülpicher Str. 77, 50937 Cologne, Germany;3. Harvard-Smithsonian Center for Astrophysics, Cambridge, MA 02138, USA;4. Division of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138, USA;5. Theoretical Chemistry, Institute for Molecules and Materials, Radboud University, Heyendaalseweg 135, 6525 AJ Nijmegen, the Netherlands;1. Department of Physics, The University of Tennessee, Knoxville, TN 37996, United States;2. Air Force Research Lab, Space Vehicles Directorate, Kirtland AFB, NM 87117, United States;3. Department of Chemistry, The University of Tennessee, Knoxville, TN 37996, United States |
| |
| Abstract: | Experimental values of kinetic energy release (T) for predissociation processes of the diatomic dications CF2+ and CCl2+ have been obtained using mass-analysed ion kinetic energy spectrometry (MIKES) on a double-focusing mass spectrometer. Both unimolecular and collision-induced processes were studied. Potential energy curves for CF2+ and CCl2+ were calculated using the semi-empirical procedure due to Hurley, and applied to the interpretation of the observed T values. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
