Eigenschaften und Zustandsdiagramme einiger silberchalkogenidsysteme |
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Authors: | Z. Bontschewa-Mladenowa V. Vassilev |
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Affiliation: | (1) Hochschule für Chemische Technologie, Lehrstuhl für Chemie und Technologie der Halbleitermaterialien und Elektronenelemente, Sofia, Bulgarien |
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Abstract: | Zusammenfassung Auf Grund einer von uns durchgeführten Untersuchung über die Zustandsdiagramme der Silberchalkogenidsysteme Ag2Te-Ag2Se, Ag2Te-Ag2S, Ag2Se-Ag2S und über die Diagonalquerschnitte Ag2Se0.5Te0.5-Ag2S, Ag2S0.5Te0.5-Ag2Se, Ag2Se0.5S0.5-Ag2Te wurden ein Projektion des Raumdiagramms der Liquidusflachen und einige der wichtigsten isothermen Schnitte des dreidimensionalen Systems Ag2Te-Ag2Se-Ag2S aufgestellt. Nach der Interpretation der Art und Lage der einzelnen Phasen wurden für jedes der Systeme die elektrischen und wärmephysikalischen Eigenschaften bei Temperaturen von der des flüssigen Stickstoffes bis zu den Temperatures des Phasenübergangs untersucht und der thermoelektrische Wirkungsgrad (Z, K–1) berechnet.
On the basis of a previous investigation on the phase diagrams of the silverchalcogenide systems Ag2Te-Ag2Se, Ag2Te-Ag2S and Ag2Se-Ag2S and the diagonal sections Ag2Se0.5Te0.5-Ag2S, Ag2S0.5Te0.5-Ag2Se and Ag2Se0.5S0.5-Ag2Te, the projections of liquidus surfaces and more characteristic isothermal sections of the Ag2Te-Ag2Se-Ag2S phase diagram were constructed. After interpretation of the types and situations of the separate phases in each of the systems studied, their electric and thermophysical properties were investigated in the temperature range from 77 K up to the temperatures of the phase transitions and the values of thermoelectric efficiency were calculated,Z, Ksu–1.
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